Cause and Prevention of Galvanic Action in Aluminum

Over the years, our customers have had questions regarding water quality related to galvanic action in aluminum manifolds. We have assembled the following information strictly as general guidelines. A water quality professional will provide expert advice when specific questions arise. Water provided by local utilities varies widely because of water chemistry in the area.

Causes:

Four conditions must be present for galvanic corrosion to occur:

  • Cathode – the more noble or least active metal. This metal has current discharge properties and will be protected from corrosion by the presence of the anode metal. Cathode examples: copper, gold, silver, nickel
  • Anode – the least noble or active metal. This metal has current acceptance properties and will corrode. Anode examples: magnesium, zinc, aluminum
  • Electrolyte – the capacity to conduct electrical current through the flow of ions. Electrolyte example: water
  • Metallic Path – metallic connection conducting electrical current

Other factors affecting the corrosiveness of water are pH, temperature, and oxygen content. Water pH should remain between 6 and 8 to minimize corrosion. Increased temperature and oxygen in water also accelerate corrosion.

Prevention:

Five ways to inhibit galvanic action in water systems:

  • Cathodic Protection – A sacrificial anode (usually a zinc or magnesium rod) is installed in the system. The material is more anodic in nature than the aluminum and draws the corrosion away from the aluminum. This is a higher maintenance solution as the anode must be replaced periodically.
  • Water Condition – Change the water treatment system. Eliminate any chlorine or floating ions and monitor the pH level of the water. Add corrosion inhibitors.
  • Material Selection – Change the ratio of dissimilar metals so it is more evenly balanced, or remove the dissimilar metals completely. Use stainless steel components.
  • Coatings – Insulate the metals with a protective coating. This is often temporary. The anodizing on our aluminum manifolds usually provides adquate protection, except in severe environments.
  • Metal Isolation – Install and insulative fitting, such as a PVC bushing or pipe connection to break the electrical connection of the metallic path.

 

Note: This information is provided solely as a service to our customers, and in no way infers any liability on the part of Burger & Brown Engineering, Inc., it’s representatives or distributors.